Dec 06, 2022 · Aqueous redox flow batteries (ARFBs) exhibit great potential for large-scale energy storage, but the cross-contamination, limited ion conductivity, and high costs of ion-exchange membranes restrict the wide application of ARFBs. Herein, we report the construction of aqueous colloid flow batteries (ACFBs) based on redox-active polyoxometalate (POM) colloid electrolytes and size-exclusive